It takes the heat of a nuclear explosion to generate a thermonuclear one.
Below, a few bits from Wikipedia that shed light on the process:
From the Fusion article:
From Nuclear binding energy:
From Nuclear weapon:
When the fission bomb is detonated, gamma rays and X-rays emitted first compress the fusion fuel, then heat it to thermonuclear temperatures. The ensuing fusion reaction creates enormous numbers of high-speed neutrons, which can then induce fission in materials not normally prone to it, such as depleted uranium. Each of these components is known as a "stage", with the fission bomb as the "primary" and the fusion capsule as the "secondary". In large, megaton-range hydrogen bombs, about half of the yield comes from the final fissioning of depleted uranium.[10]
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Fusion reactions do not create fission products, and thus contribute far less to the creation of nuclear fallout than fission reactions, but because all thermonuclear weapons contain at least one fission stage, and many high-yield thermonuclear devices have a final fission stage, thermonuclear weapons can generate at least as much nuclear fallout as fission-only weapons.
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